CELANESE HOSTAFORM® C 13031 XF 50/5339 POM
Engineered for Extreme Fuel System Environments
This advanced acetal copolymer (POM-C) is meticulously designed for enhanced resistance to aggressive fuel blends and elevated temperatures, making it a critical solution for demanding applications within the transportation industry's fuel systems. It offers superior chemical resistance, robust mechanical performance, and excellent dimensional stability, ideal for injection molding processes.
1. Introduction
1.1 Product Description and Chemical Abbreviation
Hostaform® C 13031 XF 50/5339 is an acetal copolymer, a type of polyoxymethylene (POM-C), supplied by Celanese. It is recognized as a high-strength, crystalline, thermoplastic engineering resin. The material's chemical abbreviation, in accordance with ISO 1043-1, is POM Molding compound ISO 29988- POM-K, M-GNR, 04-002 POM copolymer.
This specific grade is designed for injection molding and exhibits moderate flow characteristics, facilitating its use in various part geometries. A notable attribute is its enhanced mechanical profile, delivering approximately 10% higher strength, rigidity, and hardness compared to the C 13021 grade. This deliberate engineering choice by Celanese ensures it meets more stringent mechanical demands, offering a performance upgrade for critical components where structural integrity and durability under stress are paramount.
1.2 Key Features and Distinguishing Characteristics
- Fuel Resistance: Engineered to resist deterioration from aggressive fuel blends, solvents, various fuels, and strong alkalis. Exhibits good hydrolysis resistance vital for components exposed to moisture.
- Thermal and Oxidative Stability: High resistance to thermal and oxidative degradation, ensuring integrity and performance over extended periods in elevated temperatures and oxygen-rich environments.
- Color Coding: Distinctive yellow color (50/5339) serves as a visual identifier for fuel system components, enhancing safety during manufacturing, assembly, and maintenance.
- Laser Weldability: Also available in black (10/9022) for applications utilizing laser welding, optimizing the material for specific manufacturing processes and enhancing product reliability.
1.3 Regional Availability and Product Status
Hostaform® C 13031 XF 50/5339 is broadly available across key global regions, including North America, Europe, Asia Pacific, South and Central America, and the Near East/Africa.
2. Material Properties
The comprehensive characterization of Hostaform® C 13031 XF 50/5339 reveals a material engineered for high performance in demanding environments.
2.1 Physical Properties
| Property | Value | Unit | Test Standard |
|---|---|---|---|
| Density | 1410 - 1420 | kg/m³ | ISO 1183 |
| Melt Volume Rate (MVR) | 12 | cm³/10min | ISO 1133 |
| MVR Temperature | 190 | °C | ISO 1133 |
| MVR Load | 2.16 | kg | ISO 1133 |
| Molding Shrinkage, Parallel (flow) | 2.0 - 2.2 | % | ISO 294-4, 2577 |
| Molding Shrinkage, Transverse normal | 1.8 - 1.9 | % | ISO 294-4, 2577 |
| Water Absorption, 23°C-sat | 0.65 | % | ISO 62 |
| Humidity Absorption, 23°C/50%RH | 0.2 - 0.3 | % | ISO 62 (Sim.) |
The moderate MVR value suggests a balanced flow for injection molding, while low water and humidity absorption ensure excellent dimensional stability and simplify preprocessing.
2.2 Mechanical Properties
| Property | Value | Unit | Test Standard | Temperature (°C) |
|---|---|---|---|---|
| Tensile Modulus | 2850 - 3050 | MPa | ISO 527-1/-2 | 23 |
| Tensile Stress at Yield | 62 - 68 | MPa | ISO 527-1/-2 | 50mm/min |
| Tensile Strain at Yield | 8 - 11 | % | ISO 527-1/-2 | 50mm/min |
| Nominal Tensile Strain at Break | 28 - 30 | % | ISO 527-1/-2 | 23 |
| Flexural Modulus | 3000 | MPa | ISO 178 | 23 |
| Flexural Stress at 3.5% strain | 78 | MPa | ISO 178 | |
| Charpy Impact Strength (unnotched) | 150 - 200 | kJ/m² | ISO 179/1eU | 23 |
| Charpy Impact Strength (unnotched) | 140 - 200 | kJ/m² | ISO 179/1eU | -30 |
| Charpy Notched Impact Strength | 6.7 - 7.5 | kJ/m² | ISO 179/1eA | 23 |
| Charpy Notched Impact Strength | 6 | kJ/m² | ISO 179/1eA | -30 |
| Compressive Stress at 1% strain | 31 | MPa | ISO 604 | |
| Ball Indentation Hardness, 30s | 156 | MPa | ISO 2039-1 | |
| Tensile Creep Modulus, 1h | 2750 | MPa | ISO 899-1 | |
| Tensile Creep Modulus, 1000h | 1450 | MPa | ISO 899-1 |
High impact strength, especially at low temperatures, is crucial for automotive applications. Detailed stress-strain and secant modulus-strain diagrams are available, showing data across a wide temperature range from -40°C to 120°C, ensuring comprehensive understanding of the material's response to varying thermal conditions and sustained loads.
2.3 Thermal Properties
| Property | Value | Unit | Test Standard |
|---|---|---|---|
| Melting Temperature, 10°C/min | 170 | °C | ISO 11357-1/-3 |
| DTUL at 1.80 MPa | 102 - 107 | °C | ISO 75-1/-2 |
| DTUL at 0.45 MPa | 159 - 161 | °C | ISO 75-1/-2 |
| Coeff. of Linear Therm. Expansion, parallel | 90 E-6/K (or 1.1 E-4/°C) | E-6/K or /°C | ISO 11359-1/-2 |
| Coeff. of Linear Therm. Expansion, normal | 90 E-6/K | E-6/K | ISO 11359-1/-2 |
| Flammability @1.6mm nom. thickn. | HB class | UL 94 | UL 94 |
| Burning rate, thickness 1 mm | 61.7 | mm/min | ISO 3795 (FMVSS 302) |
These thermal properties confirm suitability for high-temperature environments, such as engine compartments and modern direct injection fuel systems, where temperatures can exceed 100°C. Flammability ratings ensure compliance with crucial safety regulations.
2.4 Electrical Properties
| Property | Value | Unit | Test Standard |
|---|---|---|---|
| Dielectric Constant (Dk), 100Hz | 4 | - | IEC 60250 |
| Dielectric Constant (Dk), 1MHz | 4 | - | IEC 60250 |
| Dissipation Factor, 100Hz | 20 E-4 | - | IEC 60250 |
| Dissipation Factor, 1MHz | 50 E-4 | - | IEC 60250 |
| Volume Resistivity, 23°C | 1E12 | Ohm*m | IEC 62631-3-1 |
| Surface Resistivity, 23°C | 1E14 | Ohm | IEC 62631-3-2 |
| Electric Strength, 23°C (AC) | 35 | kV/mm | IEC 60243-1 |
| Comparative Tracking Index (CTI) | PLC 0 | - | UL 746 |
While primarily designed for fuel system applications, Hostaform® C 13031 XF also possesses strong electrical insulating capabilities, broadening its utility for components requiring both mechanical robustness and electrical insulation.
2.5 Chemical Resistance and Fuel Compatibility
Hostaform® C 13031 XF is an acetal copolymer specifically modified to resist deterioration from aggressive fuel blends. It demonstrates good chemical resistance to various solvents, fuels, and strong alkalis, coupled with good hydrolysis resistance.
This material was specifically developed to meet the demanding requirements of modern diesel direct injection systems, which can lead to significant increases in fuel system temperature (often exceeding 100°C) and aggressive decomposition products.
Rigorous testing includes immersion in Haltermann test diesel at 100°C. Further extensive testing involved immersing Hostaform® C 13031 XF in US#2 ultra-low sulfur diesel (nominal 15 ppm sulfur) and derivatives at 90°C for 6000 hours, with weekly fuel refreshes. Results for both US#2 diesel and biodiesel blends (B20 using soybean methyl esters) showed moderate mass change levels, confirming robust performance even with increased biofuel content.
This material is specifically engineered and validated for the complex chemical and thermal environment of modern diesel and biodiesel systems, providing high confidence for automotive designers.
3. Typical Applications
Hostaform® C 13031 XF 50/5339 is primarily and specifically targeted for applications within the transportation industry's fuel systems. Its properties make it ideal for molded parts that demand higher requirements for strength, rigidity, and hardness, particularly in scenarios involving direct contact with fuels.
The material was developed to meet the stringent demands of modern diesel direct injection systems, which operate at elevated temperatures and expose materials to aggressive fuel decomposition products.
- General Fuel System Components: The distinctive yellow (50/5339) variant serves as a visual indicator of its specialized purpose.
- Laser-Welded Components: The black (10/9022) variant is specifically available for applications that incorporate laser welding, providing manufacturing flexibility.
This material is a specialized solution for high-performance, high-reliability applications where material failure could have severe consequences, making it a preferred choice over less specialized materials.
4. Processing Guidelines: Injection Molding
Hostaform® C 13031 XF 50/5339 is primarily processed using injection molding. Adhering to specific guidelines is crucial for achieving optimal part quality and performance.
4.1 Preprocessing Recommendations (Drying)
General drying is typically not necessary due to its inherently low moisture absorption, streamlining the manufacturing workflow.
However, if exposed to adverse storage conditions, drying is recommended to prevent issues like splay and odor. Use a recirculating air dryer at 100-120 °C for 3-6 hours, with a maximum layer thickness of 40 mm. Maximum residual moisture content should be 0.15%, with a maximum allowable water content of 0.2%.
4.2 Temperature Parameters
| Parameter Category | Specific Parameter | Value/Range | Unit |
|---|---|---|---|
| Drying | Drying Temperature | 100 - 120 | °C |
| Drying Time | 3 - 6 | h | |
| Max. Residual Moisture | 0.15 | % | |
| Temperature | Hopper Temperature | 20 - 30 | °C |
| Feeding Zone Temperature | 60 - 80 | °C | |
| Zone 1 Temperature | 170 - 180 | °C | |
| Zone 2 Temperature | 180 - 190 | °C | |
| Zone 3 Temperature | 190 - 200 | °C | |
| Zone 4 Temperature | 190 - 210 | °C | |
| Nozzle Temperature | 190 - 210 | °C | |
| Melt Temperature | 190 - 220 | °C | |
| Manifold Temperature | 190 - 210 | °C | |
| Mold Temperature | 80 - 120 | °C | |
| Pressure | Holding Pressure | 600 - 1200 | bar |
| Back Pressure | max. 40 | bar | |
| Speed | Injection Speed | slow-medium | - |
| Screw Speed (25mm dia.) | 150 | RPM | |
| Screw Speed (40mm dia.) | 100 | RPM | |
| Screw Speed (55mm dia.) | 70 | RPM |
These detailed temperature profiles ensure optimal melt viscosity for filling and packing, minimizing internal stresses and achieving desired part properties.
4.3 Pressure and Speed Parameters
The recommended holding pressure (600-1200 bar) allows flexibility in mold packing. Back pressure should be kept at a maximum of 40 bar. Slow to medium injection speed is advised to prevent excessive shear heating and ensure uniform mold filling. Screw speeds vary with diameter to maintain consistent shear and melt quality.
4.4 Equipment Considerations
Standard injection molding machines equipped with three-phase (15 to 25 D) plasticating screws are suitable, making the material accessible to a wider range of manufacturers without specialized equipment.
4.5 Postprocessing
Post-molding conditioning, such as moisturizing, is not necessary due to the material's low moisture absorption, further streamlining the manufacturing process and reducing production costs.
5. Regulatory Compliance and OEM Approvals
The extensive list of regulatory compliances and OEM approvals for Hostaform® C 13031 XF 50/5339 underscores its established reliability and suitability for critical applications, particularly within the automotive sector.
| Category | Standard/Specification | Compliance Status/Approval |
|---|---|---|
| Regulatory Compliance | EU-Regulation (EU) 10/2011 | Monomers and additives listed |
| FDA 21 CFR 177.2470 | Compliant | |
| UL 94 HB | UL-registered for all colors, >1.5 mm thickness | |
| Drinking water approved | Approved | |
| OEM Specifications | Bosch N28 BN22-O025 | Approved (NAT & BLK) |
| Chrysler (FCA) CPN 4270 | Approved (NATURAL) | |
| Continental TST N 055 54.11 | Approved | |
| Continental TST N 055 54.11-001 | Approved | |
| Continental TST N 055 54.30 | Approved | |
| Daimler Fuel | Approved (NAT & BLK) | |
| FORD WSK-M4D635-A2 | Approved (NAT & BLK 12) | |
| GM GMW22P-POM-C3 | Approved (NATURAL) | |
| PSA FTM69 0008 | Approved | |
| PSA 01994_14_00057 | Approved | |
| Renault PMR2020 (UB03f) | Approved | |
| VW/ Audi TL52636-A, -C | Approved | |
| Auto spec approved | Yes |
This extensive list of OEM approvals signifies that Hostaform® C 13031 XF is a highly trusted and de-risked material for automotive applications, particularly in critical fuel systems, significantly reducing qualification time and costs.
6. Important Considerations for Use
While Hostaform® C 13031 XF 50/5339 offers exceptional properties, several important considerations must be taken into account for its successful and reliable application.
- Influence of Factors on Part Properties: The properties of molded parts are influenced by material selection, additives, part design, processing conditions, and environmental exposure. Optimal performance requires a holistic approach considering all these variables.
- User Responsibility for Suitability: Users are solely responsible for determining the suitability of a particular material and part design for any contemplated use. Comprehensive validation beyond standard data sheets is essential.
- Practical Trials for Fuel Aging: Despite extensive laboratory testing, practical trials are essential before using this grade in a final product. The aging behavior of diesel fuel in a running engine is complex and not fully defined by laboratory conditions, necessitating real-world validation.
- Product Availability Status: As of June 12, 2025, the availability of Hostaform® C 13031 XF 50/5339 could not be confirmed. Direct contact with Celanese is crucial for the most current information regarding product availability and supply chain viability to avoid significant commercial risks.
7. Conclusion
Hostaform® C 13031 XF 50/5339 POM is a highly specialized and robust acetal copolymer, meticulously engineered by Celanese for the stringent demands of modern transportation industry fuel systems. Its exceptional resistance to aggressive fuel blends, hot diesel, and thermal/oxidative degradation, combined with high mechanical performance and inherent dimensional stability, positions it as a premier choice for critical components.
The material's comprehensive property data and extensive OEM approvals collectively underscore its reliability and pre-qualification for high-stakes automotive applications, significantly de-risking the material selection process.
While offering significant advantages, potential users must conduct application-specific practical trials to validate long-term performance under actual operating conditions. Furthermore, confirming current product availability directly with Celanese is imperative to ensure supply chain viability. By adhering to these recommendations, manufacturers can fully leverage the advanced capabilities of Hostaform® C 13031 XF 50/5339 for their most demanding fuel system applications.