CELANESE HOSTAFORM® C 13031 XF 50/5339 POM

Engineered for Extreme Fuel System Environments

This advanced acetal copolymer (POM-C) is meticulously designed for enhanced resistance to aggressive fuel blends and elevated temperatures, making it a critical solution for demanding applications within the transportation industry's fuel systems. It offers superior chemical resistance, robust mechanical performance, and excellent dimensional stability, ideal for injection molding processes.

1. Introduction

1.1 Product Description and Chemical Abbreviation

Hostaform® C 13031 XF 50/5339 is an acetal copolymer, a type of polyoxymethylene (POM-C), supplied by Celanese. It is recognized as a high-strength, crystalline, thermoplastic engineering resin. The material's chemical abbreviation, in accordance with ISO 1043-1, is POM Molding compound ISO 29988- POM-K, M-GNR, 04-002 POM copolymer.

This specific grade is designed for injection molding and exhibits moderate flow characteristics, facilitating its use in various part geometries. A notable attribute is its enhanced mechanical profile, delivering approximately 10% higher strength, rigidity, and hardness compared to the C 13021 grade. This deliberate engineering choice by Celanese ensures it meets more stringent mechanical demands, offering a performance upgrade for critical components where structural integrity and durability under stress are paramount.

1.2 Key Features and Distinguishing Characteristics

  • Fuel Resistance: Engineered to resist deterioration from aggressive fuel blends, solvents, various fuels, and strong alkalis. Exhibits good hydrolysis resistance vital for components exposed to moisture.
  • Thermal and Oxidative Stability: High resistance to thermal and oxidative degradation, ensuring integrity and performance over extended periods in elevated temperatures and oxygen-rich environments.
  • Color Coding: Distinctive yellow color (50/5339) serves as a visual identifier for fuel system components, enhancing safety during manufacturing, assembly, and maintenance.
  • Laser Weldability: Also available in black (10/9022) for applications utilizing laser welding, optimizing the material for specific manufacturing processes and enhancing product reliability.

1.3 Regional Availability and Product Status

Hostaform® C 13031 XF 50/5339 is broadly available across key global regions, including North America, Europe, Asia Pacific, South and Central America, and the Near East/Africa.

2. Material Properties

The comprehensive characterization of Hostaform® C 13031 XF 50/5339 reveals a material engineered for high performance in demanding environments.

2.1 Physical Properties

Property Value Unit Test Standard
Density1410 - 1420kg/m³ISO 1183
Melt Volume Rate (MVR)12cm³/10minISO 1133
MVR Temperature190°CISO 1133
MVR Load2.16kgISO 1133
Molding Shrinkage, Parallel (flow)2.0 - 2.2%ISO 294-4, 2577
Molding Shrinkage, Transverse normal1.8 - 1.9%ISO 294-4, 2577
Water Absorption, 23°C-sat0.65%ISO 62
Humidity Absorption, 23°C/50%RH0.2 - 0.3%ISO 62 (Sim.)

The moderate MVR value suggests a balanced flow for injection molding, while low water and humidity absorption ensure excellent dimensional stability and simplify preprocessing.

2.2 Mechanical Properties

Property Value Unit Test Standard Temperature (°C)
Tensile Modulus2850 - 3050MPaISO 527-1/-223
Tensile Stress at Yield62 - 68MPaISO 527-1/-250mm/min
Tensile Strain at Yield8 - 11%ISO 527-1/-250mm/min
Nominal Tensile Strain at Break28 - 30%ISO 527-1/-223
Flexural Modulus3000MPaISO 17823
Flexural Stress at 3.5% strain78MPaISO 178
Charpy Impact Strength (unnotched)150 - 200kJ/m²ISO 179/1eU23
Charpy Impact Strength (unnotched)140 - 200kJ/m²ISO 179/1eU-30
Charpy Notched Impact Strength6.7 - 7.5kJ/m²ISO 179/1eA23
Charpy Notched Impact Strength6kJ/m²ISO 179/1eA-30
Compressive Stress at 1% strain31MPaISO 604
Ball Indentation Hardness, 30s156MPaISO 2039-1
Tensile Creep Modulus, 1h2750MPaISO 899-1
Tensile Creep Modulus, 1000h1450MPaISO 899-1

High impact strength, especially at low temperatures, is crucial for automotive applications. Detailed stress-strain and secant modulus-strain diagrams are available, showing data across a wide temperature range from -40°C to 120°C, ensuring comprehensive understanding of the material's response to varying thermal conditions and sustained loads.

2.3 Thermal Properties

Property Value Unit Test Standard
Melting Temperature, 10°C/min170°CISO 11357-1/-3
DTUL at 1.80 MPa102 - 107°CISO 75-1/-2
DTUL at 0.45 MPa159 - 161°CISO 75-1/-2
Coeff. of Linear Therm. Expansion, parallel90 E-6/K (or 1.1 E-4/°C)E-6/K or /°CISO 11359-1/-2
Coeff. of Linear Therm. Expansion, normal90 E-6/KE-6/KISO 11359-1/-2
Flammability @1.6mm nom. thickn.HB classUL 94UL 94
Burning rate, thickness 1 mm61.7mm/minISO 3795 (FMVSS 302)

These thermal properties confirm suitability for high-temperature environments, such as engine compartments and modern direct injection fuel systems, where temperatures can exceed 100°C. Flammability ratings ensure compliance with crucial safety regulations.

2.4 Electrical Properties

Property Value Unit Test Standard
Dielectric Constant (Dk), 100Hz4-IEC 60250
Dielectric Constant (Dk), 1MHz4-IEC 60250
Dissipation Factor, 100Hz20 E-4-IEC 60250
Dissipation Factor, 1MHz50 E-4-IEC 60250
Volume Resistivity, 23°C1E12Ohm*mIEC 62631-3-1
Surface Resistivity, 23°C1E14OhmIEC 62631-3-2
Electric Strength, 23°C (AC)35kV/mmIEC 60243-1
Comparative Tracking Index (CTI)PLC 0-UL 746

While primarily designed for fuel system applications, Hostaform® C 13031 XF also possesses strong electrical insulating capabilities, broadening its utility for components requiring both mechanical robustness and electrical insulation.

2.5 Chemical Resistance and Fuel Compatibility

Hostaform® C 13031 XF is an acetal copolymer specifically modified to resist deterioration from aggressive fuel blends. It demonstrates good chemical resistance to various solvents, fuels, and strong alkalis, coupled with good hydrolysis resistance.

This material was specifically developed to meet the demanding requirements of modern diesel direct injection systems, which can lead to significant increases in fuel system temperature (often exceeding 100°C) and aggressive decomposition products.

Rigorous testing includes immersion in Haltermann test diesel at 100°C. Further extensive testing involved immersing Hostaform® C 13031 XF in US#2 ultra-low sulfur diesel (nominal 15 ppm sulfur) and derivatives at 90°C for 6000 hours, with weekly fuel refreshes. Results for both US#2 diesel and biodiesel blends (B20 using soybean methyl esters) showed moderate mass change levels, confirming robust performance even with increased biofuel content.

This material is specifically engineered and validated for the complex chemical and thermal environment of modern diesel and biodiesel systems, providing high confidence for automotive designers.

3. Typical Applications

Hostaform® C 13031 XF 50/5339 is primarily and specifically targeted for applications within the transportation industry's fuel systems. Its properties make it ideal for molded parts that demand higher requirements for strength, rigidity, and hardness, particularly in scenarios involving direct contact with fuels.

The material was developed to meet the stringent demands of modern diesel direct injection systems, which operate at elevated temperatures and expose materials to aggressive fuel decomposition products.

  • General Fuel System Components: The distinctive yellow (50/5339) variant serves as a visual indicator of its specialized purpose.
  • Laser-Welded Components: The black (10/9022) variant is specifically available for applications that incorporate laser welding, providing manufacturing flexibility.

This material is a specialized solution for high-performance, high-reliability applications where material failure could have severe consequences, making it a preferred choice over less specialized materials.

4. Processing Guidelines: Injection Molding

Hostaform® C 13031 XF 50/5339 is primarily processed using injection molding. Adhering to specific guidelines is crucial for achieving optimal part quality and performance.

4.1 Preprocessing Recommendations (Drying)

General drying is typically not necessary due to its inherently low moisture absorption, streamlining the manufacturing workflow.

However, if exposed to adverse storage conditions, drying is recommended to prevent issues like splay and odor. Use a recirculating air dryer at 100-120 °C for 3-6 hours, with a maximum layer thickness of 40 mm. Maximum residual moisture content should be 0.15%, with a maximum allowable water content of 0.2%.

4.2 Temperature Parameters

Parameter Category Specific Parameter Value/Range Unit
DryingDrying Temperature100 - 120°C
Drying Time3 - 6h
Max. Residual Moisture0.15%
TemperatureHopper Temperature20 - 30°C
Feeding Zone Temperature60 - 80°C
Zone 1 Temperature170 - 180°C
Zone 2 Temperature180 - 190°C
Zone 3 Temperature190 - 200°C
Zone 4 Temperature190 - 210°C
Nozzle Temperature190 - 210°C
Melt Temperature190 - 220°C
Manifold Temperature190 - 210°C
Mold Temperature80 - 120°C
PressureHolding Pressure600 - 1200bar
Back Pressuremax. 40bar
SpeedInjection Speedslow-medium-
Screw Speed (25mm dia.)150RPM
Screw Speed (40mm dia.)100RPM
Screw Speed (55mm dia.)70RPM

These detailed temperature profiles ensure optimal melt viscosity for filling and packing, minimizing internal stresses and achieving desired part properties.

4.3 Pressure and Speed Parameters

The recommended holding pressure (600-1200 bar) allows flexibility in mold packing. Back pressure should be kept at a maximum of 40 bar. Slow to medium injection speed is advised to prevent excessive shear heating and ensure uniform mold filling. Screw speeds vary with diameter to maintain consistent shear and melt quality.

4.4 Equipment Considerations

Standard injection molding machines equipped with three-phase (15 to 25 D) plasticating screws are suitable, making the material accessible to a wider range of manufacturers without specialized equipment.

4.5 Postprocessing

Post-molding conditioning, such as moisturizing, is not necessary due to the material's low moisture absorption, further streamlining the manufacturing process and reducing production costs.

5. Regulatory Compliance and OEM Approvals

The extensive list of regulatory compliances and OEM approvals for Hostaform® C 13031 XF 50/5339 underscores its established reliability and suitability for critical applications, particularly within the automotive sector.

Category Standard/Specification Compliance Status/Approval
Regulatory ComplianceEU-Regulation (EU) 10/2011Monomers and additives listed
FDA 21 CFR 177.2470Compliant
UL 94 HBUL-registered for all colors, >1.5 mm thickness
Drinking water approvedApproved
OEM SpecificationsBosch N28 BN22-O025Approved (NAT & BLK)
Chrysler (FCA) CPN 4270Approved (NATURAL)
Continental TST N 055 54.11Approved
Continental TST N 055 54.11-001Approved
Continental TST N 055 54.30Approved
Daimler FuelApproved (NAT & BLK)
FORD WSK-M4D635-A2Approved (NAT & BLK 12)
GM GMW22P-POM-C3Approved (NATURAL)
PSA FTM69 0008Approved
PSA 01994_14_00057Approved
Renault PMR2020 (UB03f)Approved
VW/ Audi TL52636-A, -CApproved
Auto spec approvedYes

This extensive list of OEM approvals signifies that Hostaform® C 13031 XF is a highly trusted and de-risked material for automotive applications, particularly in critical fuel systems, significantly reducing qualification time and costs.

6. Important Considerations for Use

While Hostaform® C 13031 XF 50/5339 offers exceptional properties, several important considerations must be taken into account for its successful and reliable application.

  • Influence of Factors on Part Properties: The properties of molded parts are influenced by material selection, additives, part design, processing conditions, and environmental exposure. Optimal performance requires a holistic approach considering all these variables.
  • User Responsibility for Suitability: Users are solely responsible for determining the suitability of a particular material and part design for any contemplated use. Comprehensive validation beyond standard data sheets is essential.
  • Practical Trials for Fuel Aging: Despite extensive laboratory testing, practical trials are essential before using this grade in a final product. The aging behavior of diesel fuel in a running engine is complex and not fully defined by laboratory conditions, necessitating real-world validation.
  • Product Availability Status: As of June 12, 2025, the availability of Hostaform® C 13031 XF 50/5339 could not be confirmed. Direct contact with Celanese is crucial for the most current information regarding product availability and supply chain viability to avoid significant commercial risks.

7. Conclusion

Hostaform® C 13031 XF 50/5339 POM is a highly specialized and robust acetal copolymer, meticulously engineered by Celanese for the stringent demands of modern transportation industry fuel systems. Its exceptional resistance to aggressive fuel blends, hot diesel, and thermal/oxidative degradation, combined with high mechanical performance and inherent dimensional stability, positions it as a premier choice for critical components.

The material's comprehensive property data and extensive OEM approvals collectively underscore its reliability and pre-qualification for high-stakes automotive applications, significantly de-risking the material selection process.

While offering significant advantages, potential users must conduct application-specific practical trials to validate long-term performance under actual operating conditions. Furthermore, confirming current product availability directly with Celanese is imperative to ensure supply chain viability. By adhering to these recommendations, manufacturers can fully leverage the advanced capabilities of Hostaform® C 13031 XF 50/5339 for their most demanding fuel system applications.

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