ABS vs PC Mechanical & Thermal Properties

When selecting a rigid thermoplastic for structural enclosures, automotive components, or electronic housings, navigating the trade-offs between Acrylonitrile Butadiene Styrene (ABS) and Polycarbonate (PC) is a critical step in initial R&D. While ABS offers excellent processability and cost efficiency, PC delivers elite mechanical robustness and thermal ceilings.To see how these mechanical boundaries translate into real-world procurement costs and industry applications, check out our master evaluation: ABS vs PC: Which One Should You Choose for Your Product?.

PC
Superior Impact
+45°C
Higher HDT
ABS
Better Processability
PC
Notch Sensitive

Mechanical Strength Showdown: Impact Energy vs. Hardness

The primary mechanical differentiator between ABS and PC lies in how their molecular structures respond to stress, particularly under shifting thermal loads.

Notched Izod Impact Strength (J/m)

PC
Polycarbonate
500 - 800 J/m
High Energy Absorption
ABS
Acrylonitrile Butadiene Styrene
150 - 400 J/m
Moderate Toughness

PC at Low Temperatures

Maintains high impact resistance down to -20°C due to flexible carbonate linkages.

ABS Brittle Transition

Rapid ductile-to-brittle transition below 0°C.

Surface Hardness vs. Rigid Notch Sensitivity

PC registers higher Rockwell Hardness (R118–R120) than ABS (R105–R110). However, PC is highly notch-sensitive. Always use generous fillet radii (R/T ≥ 0.25).

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Request the Full ABS vs PC Comparison Datasheet

Includes detailed property tables, chemical compatibility charts, and real-world application case studies.

Thermodynamic Boundaries: HDT and Dimensional Stability

Thermal load capacity dictates the functional environment of the finished product.

Thermal Property Standard ABS Unreinforced PC
HDT @ 1.82 MPa 80°C – 95°C 130°C – 140°C
Glass Transition Temp (Tg) ~105°C ~145°C
CLTE (10⁻⁵/°C) 8.0 – 10.0 6.5 – 7.0

Under 1.82 MPa load, ABS begins to deform near 85°C while PC maintains integrity up to 130°C. PC also offers superior dimensional stability with lower CLTE.

Degradation Pathways: UV Exposure & Weathering

ABS Photo-Oxidation

Butadiene rubber component vulnerable to UV. Leads to yellowing, chalking, and rapid loss of impact strength.

PC Photo-Fries Rearrangement

Surface ambering occurs, but bulk mechanical properties remain largely intact longer than ABS.

Conclusion

Use ABS for complex geometry, cost efficiency, and controlled indoor environments. Upgrade to PC for sub-zero impact performance, high-temperature structural loads, or tight dimensional tolerances. For outdoor use, both materials benefit from UV stabilizers or protective coatings.

Evaluating the raw physical data, molecular mechanics, and environmental degradation pathways of both polymers helps pinpoint the precise boundaries of each material — enabling engineers to make confident material selections that balance performance, cost, and longevity.

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